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75. Tackling the Carbonyl gem-Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2-Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction 
Gao, Bing; Zhao, Yanchuan; Hu, Mingyou; Ni, Chuanfa; Hu, Jinbo*
Chem. Eur. J. 2014, 20, 7803-7810
74. Copper-Mediated Trifluoromethylthiolation of α-Diazoesters 
Hu, Mingyou; Rong, Jian; Miao, Wenjun; Ni, Chuanfa; Han, Yongxin; Hu, Jinbo*
Org. Lett. 2014, 16, 2030 – 2033.
(Highlighted by Synfacts 2014, 10, 741)
73. Recent Advances in the Synthetic Application of Difluorocarbene 
Ni, Chuanfa; Hu, Jinbo*
Synthesis 2014, 842.
(Invited Review)
72. Deoxygenative gem-Difluoroolefination of Carbonyl Compounds with (Chlorodifluoromethyl)trimethylsilane and Triphenylphosphine 
Wang, Fei; Li, Lingchun; Ni, Chuanfa; Hu,Jinbo*
Beilstein J. Org. Chem. 2014, 10, 344 – 351.
(Invited contribution for a thematic series on organo-fluorine chemistry)
71.Stereoselective Nucleophilic Fluoromethylation of Aryl Ketones: Dynamic Kinetic Resolution of Chiral α-Fluoro Carbanions 
Xiao Shen, Wenjun Miao, Chuanfa Ni, Jinbo Hu*
Angew. Chem. Int. Ed. 2014, 53, 775 – 779.
70.Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C–F Bond Cleavage 
Hu, Mingyou; He, Zhengbiao; Gao, Bing; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo*
J. Am. Chem. Soc. 2013, 135, 17302−17305.
(Most Read Articles in 11/2013)
(Highlighted by Synfacts 2014, 10, 193)
(Highlighted by Organic Chemistry Portal)
69. Direct Monofluoromethylation of O-, S-, N-, and P-Nucleophiles with PhSO(NTs)CH2F: Accelerating Effect of α-Fluorine Substitution 
Shen, Xiao; Zhou, Min; Ni, Chuanfa; Zhang, Wei; Hu, Jinbo*
Chem. Sci. 2014, 5,117-122
68.Synthesis of gem-Difluorocyclopropa(e)nes and O-, S-, N-, and P-Difluoromethylated Compounds with TMSCF2Br 
Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo*
Angew. Chem. Int. Ed. 2013, 52, 12390–12394.
(This work was selected as the Hot Paper)
67.Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base 
Hu, Mingyou; Gao,Bin; Ni, Chuanfa; Zhang, Laijun; Hu, Jinbo*
J. Fluorine Chem. 2013, 155, 52-58.
66.Highly Stereoselective and One-Pot Synthesis of Tetra-substituted Monofluoroalkenes with Aldehydes and Fluorobis(phenylsulfonyl)methane 
Shen, Xiao; Ni, Chuanfa; Hu, Jinbo*
Chin. J. Chem. 2013, 31, 878-884.


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