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以来自TMSCF3的二氟卡宾可控插入C-Cu实现四氟亚乙基化的研究工作被Chemistry World报道!
发布时间:2019/12/6 9:07:08

 

 

德国有机氟化学专家Peer Kirsch (《现代有机氟化学》一书的作者)的评论如下:

       The insertion of CF2 during copper-catalysed trifluoromethylation of iodoarenes has been known as a side reaction for decades: the resulting products always contained a few percent of the pentafluoroethyl homologue which was nearly impossible to remove from the product. It is amazing how this undesired reaction has finally turned into something useful.

 

报道原文:PDF

报道链接:https://www.chemistryworld.com/news/simple-way-to-construct-molecules-with-perfluoroalkyl-bridges/4010811.article#/






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