Organofluorine Chemistry
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56.From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds 
Zhao, Yanchuan; Gao, Bing; Hu, Jinbo*
J. Am. Chem. Soc. 2012, 134, 5790-5793.
55.Copper-Catalyzed Di- and Trifluoromethylation of α,β-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations 
He, Zhengbiao; Luo, Tao; Hu, Mingyou; Cao, Yanjing; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 3944-3947.
54.Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters 
Zhao, Yanchuan; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 1033-1036.
53.Palladium-Catalyzed Allylation of 2,2,2-Trifluoroethyl Phenyl Sulfone: A Potential 2,2,2-Trifluoroethyl Pronucleophile 
Zhang, Wei; Zhao, Yanchuan; Ni, Chuanfa; Mathew, Thomas*; Hu, Jinbo*
Tetrahedron Lett. 2012, 53, 6565-6568.
52.Nucleophilic Fluoroalkylation of a,β-Unsaturated Carbonyls with α-Fluorinated Sulfones: Investigation of the Reversibility of 1,2-Additions and the Formation of 1,4-Adducts 
Shen, Xiao; Ni, Chuanfa; Hu, Jinbo*
HeIv. Chim. Acta, 2012, 95, 2043-2051.
51.Nucleophilic Difluoromethylation of C=N Bonds in Heterocycles with Difluoromethyl Silane Reagents 
Huang, Weizhou; Ni, Chuanfa; Zhao, Yanchuan; Zhang, Wei; Dilman, Alexander, D.; Hu, Jinbo*
Tetrahedron, 2012, 68, 5137-5144.
50.Nucleophilic Difluoromethylation of N,N-Acetals with TMSCF2SO2Ph Reagent Promoted by Trifluoroacetic Acid: A Facile Access to α-Difluoromethylated Tertiary Amines 
Huang, Weizhou; Ni, Chuanfa; Zhao, Yanchuan; Gao, Bing; Hu, Jinbo*
J. Fluorine Chem. 2012, 143, 161-166.
49.Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te) 
Hu, Mingyou; Wang, Fei; Zhao, Yanchuan; He, Zhengbiao; Hu, Jinbo*
J. Fluorine Chem. 2012, 135, 45-58.
48.Selective Fluoroalkylation of Organic Compounds by Tackling the ‘Negative Fluorine Effect’ 
Zhang, Wei; Ni, Chuanfa; Hu, Jinbo*
Top. Curr. Chem. 2012, 308, 25-44.
47.Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature 
Zhao, Yanchuan; Huang, Weizhou; Zheng, Ji; Hu, Jinbo*
Org. Lett. 2011, 13, 5342-5345.

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