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Yuwen Zeng published the aticle on JACS
Date:2013/6/17

    An unprecedented silver-mediated vicinal trifluoromethylation−iodination of arynes that quickly introduces CF3 and I groups onto aromatic rings in a single step to give o-trifluoromethyl iodoarenes has been developed. A new reactivity of AgCF3 has been revealed, and 2,2,6,6-tetramethylpiperidine plays an important role in this difunctionalization reaction.

DOI: 10.1021/ja312711c






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