Organofluorine Chemistry
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100. gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors 
Hu, Mingyou; Ni, Chuanfa; Li, Lingchun; Han, Yongxin; Hu, Jinbo*
Journal of the American Chemical Society, 2015, 137, 14496—14501. (Open Access)
(Top 20 most downloaded articles in 11-12/2015)
(Highlighted by X-MOL)
(Highlighted by Organic Chemistry Portal)
99. Brønsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides 
Luo, Tao; Zhang, Rui; Shen. Xiao; Zhang, Wei; Ni, Chuanfa; Hu, Jinbo*
Dalton Trans., 2015, 44, 19636-19641.
(Invited Contribution)
98. Chemically Oxidative Fluorination with Fluoride Ions 
Ni, Chuanfa; Jiang, Fanzhou, Zeng, Yuwen; Hu, Jinbo*
Journal of Fluorine Chemistry, 2015, 179, 3 - 13.
(Invited Review)
97. Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes 
Zeng, Yuwen; Li, Guangyu; Hu, Jinbo*
Angewandte Chemie International Edition, 2015, 54, 10773 - 10777; Angewandte Chemie, 2015, 127, 10923 - 10927.
96. Palladium-Catalyzed Monofluoromethylation of Arylboronic Esters with Fluoromethyl Iodide 
Hu, Jingyu; Gao, Bing; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo*
Organic Letters, 2015, 17, 3086 - 3089.
(Highlighted by Synfacts, see: Synfacts, 2015, 11, 0974.)
95. Carbonyl Olefination of Diaryl Ketones with Heteroaryl Sulfoxides 
Gao, Bing; Hu, Jingyu; Zhao, Yanchuan; Hu, Jinbo*
Tetrahedron Letters, 2015, 56, 4180 - 4183.
94. Recent Advances in Green Fluorine Chemistry 
Zeng, Yuwen; Hu, Jinbo*
Reports in Organic Chemistry, 2015, 5, 19 - 39; DOI: 10.2147/ROC.S80171. (Open Access)
(Invited Review)

Abstract: Fluorinated compounds are intriguing for the development of pharmaceuticals, agrochemicals, and materials, and thus, much effort has been exerted to develop more general and efficient approaches for introducing fluorine atom(s) or fluoroalkyl group(s) into organic molecules. Although many traditional methods usually cannot satisfy the simplicity and cost efficiency for industrial production and laboratorial synthesis, significant progress in green fluorine chemistry has been made in recent years, allowing efficient incorporation of fluorine into complex organic molecules. The main purpose of this review is to describe recent advances in organofluorine chemistry, with an emphasis on generality, selectivity, and environmental friendliness of related methods.

93. Fluoroalkylative Aryl Migration of Conjugated N-Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates 
He, Zhengbiao; Tan, Ping; Ni, Chuanfa; Hu, Jinbo*
Organic Letters, 2015, 17, 1838 - 1841. (Open Access)
(Top 20 Most Downloaded Articles in 04/2015 and 01-02/2016; Top 20 Most Downloaded Articles for the previous 12 months (02-04/2016))
92. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes 
Zhao, Yanchuan; Jiang, Fanzhou; Hu, Jinbo*
Journal of the American Chemical Society, 2015, 137, 5199 - 5203. (Open Access)
(Highlighted by JACS Spotlights, see: Krane, S. J. Am. Chem. Soc. 2015, 137, 5637 - 5637)
91. Advances in Transition-Metal-Mediated Di- and Monofluoroalkylations 
Ni, Chuanfa; Zhu, Lingui; Hu, Jinbo*
Acta Chimica Sinica, 2015, 73, 90 - 115.
(Invited Review)
(Highlighted on the Cover)


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